Yes you can.
If you are going to make payments on behalf of your company and deposit from a company bank account, you'll need to create a TransferWise business profile in addition to your personal profile.
Log in, click on 'Settings' and then on Business Profile. Add all relevant details about your company.
Now, in case you will be making a business payment, please make sure to choose your company name from the drop-down menu under 'Sender' and deposit funds to us from the corresponding company bank account.
Your company also needs to be verified and we'll be asking you for business identification.
If you make a payment order from your personal profile and a deposit from your company bank account (or vice versa), we're unable to match your payment order to your deposit.
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We offer live customer support and handle payments during UK business hours (Mo-Fr 9 am to 5 pm).